Tantalum(V) fluoride
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| Tantalum(V) fluoride | |
|---|---|
| Image:Tantalum(V) fluoride.jpg | |
| General | |
| Other names | tantalum pentafluoride |
| Molecular formula | TaF5 |
| Molar mass | 275.95 g/mol |
| Appearance | white powder |
| CAS number | [7783-71-3] |
| Properties | |
| Density and phase | 4.74 g/cm3, solid |
| Solubility in water | decomposes |
| Melting point | 96.8 °C |
| Boiling point | 229.5 °C |
| Hazards | |
| EU classification | not listed |
| NFPA 704 | |
| Dipole moment | 0 D |
| Hazards | |
| MSDS | External MSDS |
| Main hazards | HF source |
| NFPA 704 | |
| Flash point | nonflammable |
| R/S statement | R: 34 S: 26-27-28-36/37/39-45 |
| RTECS number | WW5775000 |
| Supplementary data page | |
| Structure and properties |
n, εr, etc. |
| Thermodynamic data |
Phase behaviour Solid, liquid, gas |
| Spectral data | UV, IR, NMR, MS |
| Related compounds | |
| Related compounds | TaCl5 NbCl5 WF6 |
| Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) Infobox disclaimer and references |
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Tantalum(V) fluoride is the chemical compound with the formula. TaF5. Characteristic of other penta and hexafluorides, TaF5 is volatile.
Contents |
[edit] Preparation
It is prepared by treating Ta metal with fluorine gas.[1] NbF5 is prepared similarly.
[edit] Structure
Solid and molten TaF5 is tetrameric, consisting of four TaF4 centers linked together via bridging fluoride atoms. Gaseous TaF5 adopts the trigonal pyramidal structure, with D3h symmetry.[2]
[edit] Reactions and derivatives
The tendency of TaF5 to form clusters in the solid state indicates the Lewis acidity of the monomer. Indeed, TaF5 reacts with fluoride sources to give the ions [TaF6]-, [TaF7]2-, and [TaF8]3-. With neutral Lewis bases, such as diethyl ether TaF5 forms adducts.
[edit] References
- ^ Priest, H. F. “Anhydrous Metal Fluorides” Inorganic Syntheses McGraw-Hill: New York, 1950; Vol. 3, pages 171-183.
- ^ Holleman, A. F.; Wiberg, E. "Inorganic Chemistry" Academic Press: San Diego, 2001. ISBN 0-12-352651-5.
[edit] External links
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