Maxwell material

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A Maxwell material is a viscoelastic material having the properties both of elasticity and viscosity. It is named for James Clerk Maxwell who proposed the model in 1867.

1 Definition
2 Effect of a sudden deformation
3 Effect of a sudden stress
4 Dynamic modulus
5 References
6 See also

[edit] Definition

The Maxwell model can be represented by a purely viscous damper and a purely elastic spring connected consecutively, as shown in the diagram. In this configuration, under an applied axial stress, the total stress, $σ T o t a l$ and the total strain, $ε T o t a l$ can be defined as follows:

σ T o t a l = σ D = σ S

ε T o t a l = ε D + ε S

where the subscript D indicates the stress/strain in the damper and the subscript S indicates the stress/strain in the spring. Taking the derivative of strain with respect to time, we obtain:

$\frac {d\epsilon_{Total}} {dt} = \frac {d\epsilon_{D}} {dt} + \frac {d\epsilon_{S}} {dt} = \frac {\sigma} {c} + \frac {1} {E} \frac {d\sigma} {dt}$

where E is the elastic modulus and c is the material coefficient of viscosity. This model describes the damper as a Newtonian fluid and models the spring with Hooke's law.

If we connect these two elements in parallel, we get a model of Kelvin-Voigt material.

In a Maxwell material, stress σ, strain ε and their rates of change with respect to time t are governed by equations of the form:

$\frac {1} {E} \frac {d\sigma} {dt} + \frac {\sigma} {c} = \frac {d\epsilon} {dt}$

or, in dot notation:

$\frac {\dot {\sigma}} {E} + \frac {\sigma} {c}= \dot {\epsilon}$

where E is a modulus of elasticity and c a "viscosity". The equation can be applied either to the shear stress or to the uniform tension in a material. In the former case, the viscosity corresponds to that for a Newtonian fluid. In the latter case, it has a slightly different meaning relating stress and rate of strain.

The model is usually applied to the case of small deformations. For the large deformations we should include some geometrical non-linearity. For the simplest way of generalizing the Maxwell model, refer to the Upper Convected Maxwell Model.

[edit] Effect of a sudden deformation

If a Maxwell material is suddenly deformed to a strain of $ε 0$ and is kept under this deformation, then the stresses would decay.

The picture shows dependence of dimensionless stress $\frac {\sigma(t)} {E\epsilon_0}$ upon dimensionless time $λ t$ :

Dependence of dimesionless stress upon dimensionless time under constant strain

If we free the material at time $t 1$ , then the elastic element will spring back by the value of

$\epsilon_\mathrm{back} = -\frac {\sigma(t_1)} E = \epsilon_0 \exp (-\lambda t_1).$

Since the viscous element would stay where it is, the irreversible component of deformation can be simplified to the expression below:

$\epsilon_\mathrm{irresversible} = \epsilon_0 \left(1- \exp (-\lambda t_1)\right).$

[edit] Effect of a sudden stress

If a Maxwell material is suddenly subjected to a stress $σ 0$ , then the elastic element would suddenly deform and the viscous element would deform with a constant rate:

$\epsilon(t) = \frac {\sigma_0} E + t \frac{\sigma_0} c$

If at some time $t 1$ we would release the material, then the deformation of the elastic element would be the spring-back deformation and the deformation of the viscous element would not change:

$\epsilon_\mathrm{reversible} = \frac {\sigma_0} E,$

$\epsilon_\mathrm{irreversible} = t_1 \frac{\sigma_0} c.$

The Maxwell Model is not ideal for predicting the creep behavior of a material since it describes the strain relationship with time as linear.

If a small stress is applied for a sufficiently long time, then the irreversible stresses become large. Thus, Maxwell material is a type of liquid.

[edit] Dynamic modulus

The complex dynamic modulus of Maxwell material would be:

$E^*(\omega) = \frac 1 {1/E - i/(\omega c) } = \frac {Ec^2 \omega^2 +i \omega E^2c} {\omega^2 c^2 + E^2}$

Thus, the components of the dynamic modulus are :

$E_1(\omega) = \frac {Ec^2 \omega^2 } {c^2 \omega^2 + E^2}$

and

$E_2(\omega) = \frac {\omega E^2c} {\omega^2 c^2 + E^2}$

Relaxational spectrum for Maxwell material

The picture shows relaxational spectrum for Maxwell material.

Black curve	dimensionless elastic modulus $\frac {E_1} {E}$
Red curve	dimensionless modulus of losses $\frac {E_2} {E}$
Yellow curve	dimensionless apparent viscosity $\frac {E_2} {\omega c}$
X-axis	dimensionless frequency $\frac {\omega} {\lambda}$ .