Thioacetic acid

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Skeletal formula of thioacetic acid

Thioacetic acid is an organic compound with the molecular formula CH₃COSH. It is the sulfur equivalent of acetic acid (AcSH) with a lower boiling point (88-91.5°C). It is used in organic chemistry for the introduction of thiol groups in molecules.

In one application the reagent is used with AIBN in a free radical mediated nucleophilic addition to an exocyclic alkene forming a thioester ^[1] :

[edit] References

1. ^ Synthesis of methyl 6-deoxy-4-O-(sodium sulfonato)-α-Ltalopyranoside, its C-4 epimer and both isosteric [4-C-(potassium sulfonatomethyl)] derivativesLászló Lázár, Magdolna Csávás, Anikó Borbás, Gyöngyi Gyémánt, and András Lipták ARKIVOC 2004 (vii) 196-207 Link

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Categories: Reagents for organic chemistry | Sulfur compounds

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• This page was last modified 17:16, 15 February 2007 by Wikipedia user Stepa. Based on work by Wikipedia user(s) Benjah-bmm27 and V8rik.
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